Don't worry about the orange layer it is not an infection. It is debris due to improper cleaning.
The matter of concern for you right now is the impacted molar in that region. Because it is:
1.Causing Pain.
2.Cutting the buccal mucosa.
3.Creating hindrance in proper cleaning.
Next Steps
1.Extraction of the impacted molar.
2.Oral prophylaxis to be done.
Health Tips
1.Lukewarm saline rinse.
2.Night brushing.
3.Rinsing after every meal.
4.Mouthwash rinse.