Grilinctus BM contains terbutalin which can cause tremor as side effects. This might be the cause of your mother's unexplained shivering and uneasiness. However, you should check her body temperature with a thermometer. Fever may be associated with acute cough. Of there is fever, this can cause shivering and chill.
Next Steps
Check temperature, follow up with your doctor who prescribed the cough syrup. If he is not available, can contact me for further advice.
Health Tips
Check oxygen saturation