It's never too late. Children look up to parents for setting limits. You must start immediately communicating unacceptability of his improper behaviour EVERY time he shows up the same. Do it consistently, they eventually learn to inhibit to NO . You may also use extinction instead of any other kind of punishment if he is not inhibiting (  https://youaremom.com/parenting/learn-how-to-be-a-mom/behavior/extinction-technique/). Also reward him when he behaves good. Involve him in small tasks of younger siblings care. Do not increase their distance .

Be consistent. Establish a daily routine so that your child knows what to expect. ... Plan ahead. Run errands when your child isn't likely to be hungry or tired. ... Let your child make appropriate choices. Avoid saying no to everything. ... Praise good behavior. ... Avoid situations likely to trigger tantrums